2013年5月26日星期日

Investigators have determined that ammonium nitrate was the cause of the explosion at a West


Investigators have determined that ammonium nitrate was the cause of the explosion at a West,  fertiliser plant last month that left 14 people dead and some 200 injured, a spokeswoman for the Texas state fire marshal's office said on Tuesday.
"The investigators have been able to narrow down the origin to the fertilizer and seed building on site, and we also know that what caused the explosion was the ammonium nitrate," said Rachel Moreno, a spokeswoman for the Texas state fire marshal's office. "What we don't know is exactly why."

The fire marshal's office has been leading the investigation of the April 17 blast, along with the federal Bureau of Alcohol, Tobacco, Firearms and Explosives (ATF).
Ammonium nitrate is a dry fertiliser mixed with other fertilisers such as phosphate and applied to crops to promote growth. It can be combustible under certain conditions, and was used as an ingredient in the Oklahoma City bombing in 1995 that left 168 people dead.

Ammonium nitrate - research history and main purposes


Ammonium nitrate - research history
Ammonium nitrate in 1659, German J.R. Gelaobeier first obtained ammonium nitrate. The end of the nineteenth Century, the Europeans with ammonium sulfate and nitrate by double decomposition reaction of ammonium nitrate production. Due to the large-scale development of synthetic ammonia industry, ammonium nitrate production was rich in raw materials, in the middle of twentieth Century has obtained the rapid development, the Second World War, some countries established the ammonium nitrate plant, used in the manufacture of explosives. In 60, the ammonium nitrate was the leading varieties of nitrogen fertilizer. China has established a number of ammonium nitrate plant in the 50's..
In 40, in order to prevent hygroscopicity and caking of ammonium nitrate, were coated with paraffin wax and other organic matter, because it had detonated explosion in shipping. Therefore, some countries have established the relevant agricultural ammonium nitrate production, storage and transportation management regulations, some countries have even banned ammonium nitrate transport and fertilizer use, are only allowed to use it with calcium ammonium nitrate and calcium carbonate mixture. At the beginning, calcium ammonium nitrate containing N20.5%, equivalent to about 60% containing ammonium nitrate. Now content increased to N26%, the equivalent of 75% containing ammonium nitrate.
Because later mastered the use of ammonium nitrate, some countries such as France, the Soviet Union, Romania, the United States of America and Britain, allowing the ammonium nitrate directly used as fertilizer, but for the safe use of the product standards. For example: the United States of America fertilizer association rules of solid ammonium nitrate for agricultural use of pH shall not be less than 4 (10% of ammonium nitrate in aqueous solution containing C PH); shall not exceed 0.2%; S shall not exceed 0.01%; Cl- containing not more than 0.15%.
Ammonium nitrate - main purposes
Agriculture as a cotton, flax, hemp, tobacco and vegetable crops such as fertilizer, the effect is very good; also used in compound fertilizer manufacturing potassium, phosphorus, calcium and so on. Explosive industry for manufacturing perchlorate explosive, ammonium nitrate fuel oil and slurry explosives and other raw materials. Making a two oxidation nitrogen, nitrous oxide used in pharmaceutical industry (anesthetic), vitamin B. Manufacturing alkali-free glass used in glass industry. In addition, the refrigerant, can also be used to manufacture micro bacteria agent, fireworks, music bug agent, catalyst. [1]
Used as an oxidizing agent, refrigerant, fireworks and explosive materials.

2013年4月15日星期一

Urea Ammonium Nitrate Solution




Formula: CH4N2O+NH4NO3+H2O

Properties and applications:
It is used as the Fertilizer to spray on trees and for the farming. It is included in the Chemical Family of Nitrogen Fertilizer Solution. It is not easy to burn. The normal form of product is liquid. It can supply the abundant nutrition to the plant.
The causticity is low and the safety is high. It is wide used in overseas. Now the product has supplied to Australia market.

Specification


Product A
Product B
Substance
Index
Index
Appearance
Colorless liquid, light spicy ammonia smell
Colorless liquid, light spicy ammonia smell
Total N content  %
30-30.3%
32-32.3%
Ammonium Nitrate Content  %
40-44%
42--47%
Urea content  %
31-34%
34-37%
Moisture  %
29-22%
24-16%
Free ammonia   %
≤0.05%
≤0.05%
Solubility(0-2℃)
100%
100%
PH value ( in 10% AN solution)
≤0℃
≤0℃
Crystallization temperature
6.0-7.5
6.0-7.5
Density(25℃)
1.3(1.30-1.31)
1.3(1.315-1.325)
Heavy metal
4ppm
4ppm

Package: the liquid container bags 20-25 tons/ FCL

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CALCIUM NITRATE



Molecular formula: Ca (NO3)2·4H2O
Molecular weight: 236.15

Properties and applications:
Calcium Nitrate is colorless and transparent uniclinal crystal, which is soluble in water, methanol and ethanal and is easily moisture absorbing in the air. As an oxidizing agent, it is burnable and explosible with going off while exposed to organic substance and sulphur. Calcium Nitrate is primarily applied as flocculant for rubber emulsion, petroleum exploration, effluent treatment, etc. In agriculture it is used as rapid efficiency fertilizer in acidic soil and in cultivation without soil. In light industry it is used to produce fireworks and tungsten lamp hood. In national defense industry it is used to produce explosives. In electro instrument industry it is used to coat cathode. Also it is a raw material for dyeing process and nitrate production.


Specification

Item

Quality index
First.G.
Second.G.
Calcium Nitrate,%≽
  99.2
99.0
Water insolubles,%≽
0.01
0.05
Sulphates,%≽
0.02
0.04
Heavy Metal,%≽
0.0005
0.0005
Iron,%≽
0.0007
0.0007
PH Value
4.0-7.0
Packing: in 25kg net PP/PE bags or as per customers demands
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Calcium Ammonium Nitrate



Calcium Ammonium Nitrate

Molecular formula: 5Ca (NO3)2·NH4NO3·10H2O
Molecular weight: 1080.71

Properties and applications:  It is a new Nitrogenous and Calcareous fertilizer with characteristics of high efficiency and quickly make-up Nitrogen, applied in greenhouse and large-area farmland. It improves the soil and granulates the soil making it anti-caking. It guarantees fruits in gay colors and increases carbohydrate contents in fruits.

Specification

Item
Standard  %
Assay                  
  ≥ 76
Ammonium Nitrate     
6-10
Moisture              
12-16
Calcium                 
≥18.5
Water-insolubles           
≤0.2
Iron                    
≤0.005
Chloride                 
≤0.02
PO4                    
≤0.05
PH
5-7
Packing: in 25kg net PP/PE bags or as per customers demands

Urea



 Urea

Molecular formula: CO (NH2)2

Properties and applications:It is white or little red solid grain, and show little alkalescence. It also can be hydrolyzed and shrinked. It is mainly used in synthetic resin, medicine, dye, painting, food, dynamite and fertilizers etc.
Specification

Nitrogen content
≥ 46%
Free water
≤ 0.5%
Biuret
≤1.0%
Particle size(2.0-4.75mm):
≥90%

Packing: in 50kg net PP/PE bags or as per customers demands
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2013年4月10日星期三

Chemical Pure Ammonium Nitrate


Chemical Pure Ammonium Nitrate (CPAN)

Quick Overview
Ammonium Nitrate is white prilled crystal, which has strong moisture absorption and agglomeration. It easily explodes under the action of calefaction or detonation agent. And it is easily soluble in water, methanol, acetone and liquid ammonia. It is mainly used in making ammonium nitrate explosives, emulsion explosives, refrigerating agent and nitrogen oxide adsorbing agent, as well as glass industry, medicine and fertilizers etc.

Product Description
Molecular formula: NH4NO3
Molecular weight: 80.04
Properties and applications: Ammonium Nitrate is white prilled crystal, which has strong moisture absorption and agglomeration. It easily explodes under the action of calefaction or detonation agent. And it is easily soluble in water, methanol, acetone and liquid ammonia. It is mainly used in making ammonium nitrate explosives, emulsion explosives, refrigerating agent and nitrogen oxide adsorbing agent, as well as glass industry, medicine and fertilizers etc.



Specification
Substance :
Chemical Pure Ammonium Nitrate
(Emulsion and Fertilizer )
Dangerous Goods Class:
5.1 Oxidize Agent
UN Number:
1942
Appearance:
No visible impurities
Ammonium Nitrate Content(dry base):
99.5%min
Nitrogen :
34.7%min
Moisture:
0.6%max
PH value ( in 10% AN solution) :
4min
Insoluble (in 10% nitric acid) :
0.2%max
Particle Size:
1.0-2.8mm, 85% min
Average prill anti-pressure N/pc:
5
Anti caking :
none
Packing : in 25kg net PP/PE bags or as per customers demands
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